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pyruvate + H+ → (S)-2-acetolactate + CO2 (R545)
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2-oxoglutarate + L-valine ↔ 3-methyl-2-oxobutanoate + L-glutamate (R635)
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(2R)-2,3-dihydroxy-3-methylbutanoate → H2O + 3-methyl-2-oxobutanoate (R1255)
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(2R)-2,3-dihydroxy-3-methylbutanoate + NADP+ ↔ NADPH + H+ + (S)-2-acetolactate (R1241)
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L-valine → L-valine (R00811)
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NADH + NADP+ + H+ → NADPH + NAD+ + H+ (R427)
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NAD+ + (R)-lactate ← NADH + pyruvate + H+ (R504)
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formate + acetyl-CoA ↔ coenzyme A + pyruvate (R278)
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H2O + NAD+ + L-valine ↔ NADH + 3-methyl-2-oxobutanoate + H+ + ammonium (R10439)
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L-valine + H+ → L-valine + H+ (R00882)
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D-gluconate 6-phosphate → H2O + 2-dehydro-3-deoxy-D-gluconate 6-phosphate (R1789)
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2-dehydro-3-deoxy-D-gluconate 6-phosphate → pyruvate + D-glyceraldehyde 3-phosphate (R1404)